The Tsarina valued Anna's devotion to her and befriended her, ignoring women of more distinction at the court. Anna married Alexander Vasilievich Vyrubov, a naval officer, even though she was warned by Rasputin that the marriage would be an unhappy one. The couple eventually divorced. Her mother reportedly told interrogators following the Russian Revolution that Vyrubov "proved to be completely impotent, with an extremely perverse sexual psychology that manifested itself in various sadistic episodes in which he inflicted moral suffering on her and evoked a feeling of utter disgust." Although her memoirs testify to the contrary, she is often credited with the introduction of
Rasputin to the family of
Tsar Nicholas II. For a long time she served as a go-between for the royal family and Rasputin.
During World War I she trained as a
Red Cross nurse and nursed soldiers along with the Tsarina and the Tsarina's two older daughters,
Grand Duchess Olga Nikolaevna of Russia and
Grand Duchess Tatiana Nikolaevna of Russia. She was injured in a train accident in January 1915 and credited Rasputin with saving her with his prayers. Following the Russian Revolution, Anna Vyrubova underwent a medical examination to prove her
virginity. The provincial investigator concluded that she was too naive and unintelligent to have had any influence over the Tsarina. Vyrubova escaped the
Bolshevik revolution by fleeing to
Finland.