Dirac noticed an analogy between the old
Poisson brackets of
classical mechanics and the recently-proposed quantization rules in
Werner Heisenberg's matrix formulation of quantum mechanics. This observation allowed Dirac to obtain the
quantization rules in a
novel and more illuminating manner. For this work, published in 1926, he received a
Ph.D. from
Cambridge.
In
1928, building on
Wolfgang Pauli's work on non-relativistic
spin systems, he proposed the
Dirac equation as a
relativistic equation of motion for the
wavefunction of the
electron. This work led Dirac to predict the existence of the
positron, the electron's
antiparticle, which he interpreted in terms of what came to be called the
Dirac sea. The positron was subsequently observed by
Carl Anderson in 1932. Dirac's equation also contributed to explaining the origin of
quantum spin as a relativistic phenomenon.
The necessity of electron matter being created and destroyed in
Enrico Fermi's 1934 theory of
beta decay, however, led to a reinterpretation of Dirac's equation as a "classical"
field equation for any point matter of spin ħ/2, itself subject to quantization conditions involving anti-
commutators. Thus reinterpreted, the Dirac equation is as central to theoretical physics as the
Maxwell, Yang-Mills and
Einstein field equations. Dirac is regarded as the founder of
quantum electrodynamics, being the first to use that term. He also introduced the idea of
vacuum polarization in the early 1930s.
Dirac's
Principles of Quantum Mechanics, published in
1930, is a landmark in the
history of science. It quickly became one of the standard textbooks on the subject and is still used today. In that book, Dirac incorporated the previous work of
Werner Heisenberg on “Matrix Mechanics” and of
Erwin Schrödinger on “Wave Mechanics” into a single mathematical formalism that associates measurable quantities to operators acting on the
Hilbert space of vectors that describe the state of a physical system. The book also introduced the
bra-ket notation and the
delta function, which are now universally used.
Guided by a comment in Dirac's textbook and by Dirac's 1933 article "The
Lagrangian in quantum mechanics" (published in the
Soviet journal
Physikalische Zeitschrift der Sowjet Union),
Richard Feynman developed the
path integral formulation of quantum mechanics in 1948. This work would prove exceedingly useful in relativistic
quantum field theory, in part because it is based on the
Lagrangian, whose relativistic invariance is explicit, while the invariance is only implicit in the
Hamiltonian formulation.
In 1931 Dirac showed that the existence of a single
magnetic monopole in the universe would suffice to explain the observed quantization of
electrical charge. This proposal received much attention, but there is to date no convincing evidence for the existence of magnetic monopoles.
He married
Eugene Wigner's sister, Margit, in
1937. He adopted Margit's two children, Judith and
Gabriel. Paul and Margit Dirac had two children together, daughters Mary Elizabeth and Florence Monica.